Photochemical reactions of organotungsten compounds of cymantrene series with triphenylphosphine

  • A. N. Nesmeyanov
  • E. G. Perevalova
  • L. I. Leont'eva
  • E. V. Shumilina
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Conclusions

  1. 1.

    The tungsten σ-(π-cyclopentadienyl)manganesedicarbonyltriphenylphosphine complexes (CO)2(PPh3)MnC5H4W(CO)3Cp and (CO)2(PPh3)MnC5H4,COW(CO)3Cp were obtained.

     
  2. 2.

    The photochemical reactions of (CO)2(PPh3)MnC5H4W(CO)3Cp and (CO)2(PPh3)MnC5H4COW(CO)3Cp with PPh3 gave the products of replacing the CO group on the tungsten atom by PPh3, and respectively (CO)2(PPh3)MnC5H4W(CO)2(PPh3)Cp and (CO)2(PPh3)MnC5H4,COW(CO)2 (PPh3)Cp.

     

Keywords

Tungsten PPh3 Photochemical Reaction Triphenylphosphine Cymantrene 

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Literature cited

  1. 1.
    A. N. Nesmeyanov, E. G. Perevalova, E. V. Shumilina, and L. I. Leont'eva, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 2328.Google Scholar
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    Monograph: Methods in Heteroorganic Chemistry [in Russian], Chapter 15, Nauka (1974), p. 824.Google Scholar
  6. 6.
    A. N. Nesmeyanov, E. G. Perevalova, L. I. Leont'eva, and E. V. Shumilina, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 1156.Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • A. N. Nesmeyanov
    • 1
  • E. G. Perevalova
    • 1
  • L. I. Leont'eva
    • 1
  • E. V. Shumilina
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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