Dimeric complexes of Pd(II) with imidazoline nitroxyl radical that contain the Pd-C bond and halogen bridge atoms

  • V. I. Ovcharenko
  • S. V. Larionov
  • G. N. Mironova
  • L. B. Volodarskii
Brief Communications

Conclusions

  1. 1.

    The orthometalation reaction was used to synthesize some Pd(II) complexes that contain a stable radical with the Pd-C bond.

     
  2. 2.

    It was established that the complexes have a dimeric structure and bridge halogen atoms.

     

Keywords

Halogen Halogen Atom Stable Radical Imidazoline Nitroxyl 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    V. I. Ovcharenko, S. V. Larionov, R. Z. Sagdeev, and L. B. Volodarskii, Zh. Strukt. Khim.,19, 163 (1978).Google Scholar
  2. 2.
    M. I. Bruce, Angew. Chem.,16, 73 (1977).Google Scholar
  3. 3.
    C. Cope and R. W. Siekman, J. Am. Chem. Soc.,87, 3272 (1965).Google Scholar
  4. 4.
    C. Cope and E. Fridrich, J. Am. Chem. Soc.,90, 909 (1968).Google Scholar
  5. 5.
    A. Kasahara, K. Tanaka, and T. Izumi, Bull. Chem. Soc. Jpn.,42, 1702 (1969).Google Scholar
  6. 6.
    G. M. Zhidomirov and A. L. Buchachenko, Zh. Strukt. Khim.,8, 1110 (1967).Google Scholar
  7. 7.
    V. N. Parmon, A. I. Kokorin, and G. M. Zhidomirov, Zh. Strukt. Khim.,18, 132 (1977).Google Scholar
  8. 8.
    R. A. Sadykov, R. Z. Sagdeev, Yu. N. Molin, V. I. Ovcharenko, S. V. Larionov, and L. B. Volodarskii, Koord. Khim.,3, 71 (1977).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • V. I. Ovcharenko
    • 1
  • S. V. Larionov
    • 1
  • G. N. Mironova
    • 1
  • L. B. Volodarskii
    • 1
  1. 1.Institute of Inorganic ChemistrySiberian Branch of the Academy of Sciences of the USSRNovosibirsk

Personalised recommendations