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Interaction of diethyl thiophosphite with phenolic mannich bases

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The interaction of phenolic Mannich bases with diethyl thiophosphite forms o-hydroxybenzylthiophosphonates, which undergo Pishchimuka rearrangement. Diethyl thiophosphite here disproportionates by reaction with diethylamine to form NN-diethyl O-ethyl amidophosphite and diethyl phosphite.

  2. 2.

    α-Substituted methyldiethylamines react with diethyl thiophosphite to form OO-diethyl NN-diethylaminomethylthiophosphonate.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch of the Academy of Sciences of the USSR, USSR

    B. E. Ivanov, S. S. Krokhina, I. S. Ryzhkina, V. I. Gaidai & V. N. Smirnov

Authors
  1. B. E. Ivanov
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  2. S. S. Krokhina
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  3. I. S. Ryzhkina
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  4. V. I. Gaidai
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  5. V. N. Smirnov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 615–618, March, 1979.

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Ivanov, B.E., Krokhina, S.S., Ryzhkina, I.S. et al. Interaction of diethyl thiophosphite with phenolic mannich bases. Russ Chem Bull 28, 569–572 (1979). https://doi.org/10.1007/BF00924835

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  • DOI: https://doi.org/10.1007/BF00924835

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