Conclusions
We have developed a method for the synthesis of silicon-containing polyenes from butadiene and trimethylvinylsilane or trimethoxyvinylsilane with a Ni-containing catalyst system. We suggest a reaction sequence for the cooligomerization process.
Similar content being viewed by others
Literature cited
M. Hara, K. Ohno, and J. Tsuji, Chem. Commun.,1971, 247.
M. F. Lappert, T. A. Nile, and S. Takahashi, J. Organomet. Chem.,72, 425 (1974).
J. Rejhon and J. Hetflejs, Coll. Czech. Chem. Commun.,40, 3190 (1975).
V. P. Yur'ev (Yurjev), I. M. Salimgareeva, O. Zh. Zhebarov, and G. A. Tolstikov, Fourth International Symposium on Organosilicon Chemistry, Vol. 1, Moscow (1975), p. 78.
V. P. Yur'ev, I. M. Salimgareeva, O. Zh. Zhebarov, I. I. Furlei, and L. M. Khalilov, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 204.
G. Wilke, Angew. Chem. Int. Ed.,2, 105 (1963);5, 151 (1966).
P. Heimbach, P. W. Jolly, and G. Wilke, Adv. Organomet. Chem.,8, 29 (1970).
S. S. Shavanov, U. M. Dzhemilev, and G. A. Tolstikov, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 1427.
O. S. Vostrikova, U. M. Dzhemilev, and G. A. Tolstikov, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 2018.
I. S. Akhrem, D. V. Avetisyan, R. S. Vartanyan, and M. E. Vol'pin, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 253.
V. P. Yur'ev, G. Gailyunas, F. G. Yusupova, G. A. Tolstikov, and I. Kh. Aminev, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 866.
A. N. Egorochkin, M. L. Khidekel, V. A. Ponomarenko, G. Ya. Zueva, and G. A. Razuvaev, Izv. Akad. Nauk SSSR, Ser. Khim.,1964, 372.
D. E. Dorman, M. Jantelat, and J. Roberts, J. Org. Chem.,36, 2757 (1971).
V. I. Khvostenko, V. P. Yur'ev, I. Kh. Aminev, G. A. Tolstikov, and S. R. Rafikov, Dokl. Akad. Nauk SSSR,202, 861 (1972).
I. I. Furlei, V. P. Yur'ev, V. I. Khvostenko, G. A. Tolstikov, and S. R. Rafikov, Dokl. Akad. Nauk SSSR,222, 1163 (1975).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 599–604, March, 1979.
Rights and permissions
About this article
Cite this article
Yusupova, F.G., Gailyunas, G.A., Furlei, I.I. et al. Linear cooligomerization of vinylsilanes with butadiene as a method for the synthesis of silicon-containing polyenes. Russ Chem Bull 28, 552–557 (1979). https://doi.org/10.1007/BF00924831
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00924831