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Production of regular, linear isoprene oligomers in the presence of nickel-containing homogeneous catalysts

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The oligomerization of isoprene was studied in the presence of nickel complexes activated by o- and m-borates.

  2. 2.

    The borates, in contrast to phosphorus-containing activators, direct the reaction primarily towards the formation of linear trimers and tetramers of isoprene, namely, 3-methylene-7,11-dimethyl-1-trans-6,11-dodecatriene, 2,6,10-trimethyl-1-trans-3,5,10-dodecatriene, and 2,6,10,14-tetramethyl-1-trans-3,6,10,14-hexadecapentane.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch of the Academy of Sciences of the USSR, Ufa

    U. M. Dzhemilev, G. M. Latypov, G. A. Tolstikov & O. S. Vostrikova

Authors
  1. U. M. Dzhemilev
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  2. G. M. Latypov
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  3. G. A. Tolstikov
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  4. O. S. Vostrikova
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Additional information

Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 553–557, March, 1979.

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Dzhemilev, U.M., Latypov, G.M., Tolstikov, G.A. et al. Production of regular, linear isoprene oligomers in the presence of nickel-containing homogeneous catalysts. Russ Chem Bull 28, 509–512 (1979). https://doi.org/10.1007/BF00924822

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  • DOI: https://doi.org/10.1007/BF00924822

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