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NMR study of the exchange of trimethyltin phenolate, thiophenolate, and halides in toluene

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study of PMR spectra shows that the rate of exchange of trimethyltin thiophenolate with trimethyltin halides and phenolate in toluene varies inversely with the temperature.

  2. 2.

    The rate of exchange in Me3SnX + Me3SnPh systems is dependent on the nature of the X group, increasing in the order: Br<Cl<PhO at room temperature and below. The order of increase above 60°C is: PhO<Br<Cl.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    E. D. Korniets, L. A. Fedorov, D. N. Kravtsov & É. I. Fedin

Authors
  1. E. D. Korniets
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  2. L. A. Fedorov
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  3. D. N. Kravtsov
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  4. É. I. Fedin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 525–529, March, 1979.

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Korniets, E.D., Fedorov, L.A., Kravtsov, D.N. et al. NMR study of the exchange of trimethyltin phenolate, thiophenolate, and halides in toluene. Russ Chem Bull 28, 483–487 (1979). https://doi.org/10.1007/BF00924817

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  • DOI: https://doi.org/10.1007/BF00924817

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