Conclusions
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1.
A study has been made of the kinetics of the thermal decomposition of hexafluoroisopropylidene-p,p′-diphenyldiacyl diazide in bulk, in hexafluoroisopropylidene-p,p′-diphenyldiacyl diazide solution, and in solution in various solvents, working over the interval from 55 to 95°C.
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2.
Thermal breakdown in solution follows a first-order equation, the rate being essentially independent of the nature of the solvent.
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3.
Departures from the Arrhenius law are observed in the breakdown of acyl azide in the solid phase.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 520–524, March, 1979.
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Korsunskii, B.L., Tiger, R.P., Malyushkina, L.N. et al. The kinetics of the thermal decomposition of hexafluoroisopropylidene-p,p′-diphenyldiacyl diazide in bulk and in solution. Russ Chem Bull 28, 478–483 (1979). https://doi.org/10.1007/BF00924816
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DOI: https://doi.org/10.1007/BF00924816