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The decomposition of tert-butyl hydroperoxide catalyzed by trivalent chromium stearate

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Under the action of chromium stearate, free radicals of tert-butyl hydroperoxide are formed through a bimolecular reaction in chlorobenzene solution.

  2. 2.

    Although the overall breakdown of the hydroperoxide can be described by a second-order equation, the reaction is a complex radical-initiated chain process.

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Literature cited

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Authors and Affiliations

  1. Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    L. G. Giniatullina & V. M. Solyanikov

Authors
  1. L. G. Giniatullina
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  2. V. M. Solyanikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 510–514, March, 1979.

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Giniatullina, L.G., Solyanikov, V.M. The decomposition of tert-butyl hydroperoxide catalyzed by trivalent chromium stearate. Russ Chem Bull 28, 469–473 (1979). https://doi.org/10.1007/BF00924814

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  • DOI: https://doi.org/10.1007/BF00924814

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