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Identification of structure and study of configuration of reaction products of endo-dicyclopentadiene with phenols by the1H and13C NMR method

  • V. P. Lezina
  • A. U. Stepanyants
  • A. S. Murakhovskaya
  • V. R. Melikyan
  • L. L. Vasil'eva
  • K. I. Zimina
Brief Communications
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Conclusions

  1. 1.

    It was established by the13NMR spectroscopy method that Wagner-Meerwein rearrangement occurs when endo-dicyclopentadiene is reacted with phenol and the cresols, which leads to an exo-orientation of the cyclopentene ring.

     
  2. 2.

    The exo-orientation of the aromatic substituent was proved by an analysis of the1H NMR spectrum.

     

Keywords

Spectroscopy Phenol Spectroscopy Method Cresol Cyclopentene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • V. P. Lezina
    • 1
    • 2
  • A. U. Stepanyants
    • 1
    • 2
  • A. S. Murakhovskaya
    • 1
    • 2
  • V. R. Melikyan
    • 1
    • 2
  • L. L. Vasil'eva
    • 1
    • 2
  • K. I. Zimina
    • 1
    • 2
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow
  2. 2.I. M. Gubkin Institute of the Petrochemical and Gas IndustryMoscow

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