Conclusions
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1.
The palladium chloride-dimethyl sulfoxide complex is highly active in the reactions for the hydrogénation and isomerization of allylamine.
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2.
Allylamine is simultaneously fixed in the intermediate complex at both the C=C bond and the amino group.
Literature cited
L. Kh. Freidlin, N. M. Nazarova, and Yu. A. Kopyttsev, Izv. Akad. Nauk SSSR, Ser. Khim., 201 (1972).
N. M. Nazarov, L. Kh. Freidlin, Yu. A. Kopyttsev, and T. I. Varava, ibid., 1422 (1972).
L. Kh. Freidlin, Yu. A. Kopyttsev, and N. M. Nazarova, ibid., 700 (1973).
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Deceased.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 438–440, February, 1974.
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Nazarova, N.M., Freidlin, L.K. & Kopyttsev, Y.A. Study of hydrogenation of allylamine in presence of palladium chloride-dimethyl sulfoxide complex. Russ Chem Bull 23, 406–407 (1974). https://doi.org/10.1007/BF00924699
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DOI: https://doi.org/10.1007/BF00924699