Conclusions
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1.
Fluoroketones easily add betizoyl chloride in the presence of catalytic amounts of pyridine to give the benzoates of fluoro-substituted chloroisopropanols.
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2.
When pentafluoroacetone is heated with fluoroketones in the presence of equivalent amounts of pyridine, the labile hydrogen atom is replaced and the pyridinium salts of the correspondingβ-hydroxy-ketones are formed.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 387–392, February, 1974.
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Utebaev, U., Abduganiev, E.G., Rokhlin, E.M. et al. Synthesis and some reactions of pentafluoroacetone. Russ Chem Bull 23, 352–357 (1974). https://doi.org/10.1007/BF00924686
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DOI: https://doi.org/10.1007/BF00924686