Reaction of carbene of cyclohexadienone type with multiple bonds of conjugated dienes

  • G. A. Nikiforov
  • B. D. Sviridov
  • V. V. Ershov
Organic and Biological Chemistry

Conclusions

  1. 1.

    The 1,2-addition products are formed initially when the cyclohexadienone carbene is reacted with the multiple bonds of conjugated dienes, which are isomerized under the conditions for the thermolysis of the quinone diazide, but are stable under photolysis conditions at 5–7°.

     
  2. 2.

    The rate of the thermal isomerization of the 1,2-addition products was studied.

     

Keywords

Quinone Diene Photolysis Carbene Thermolysis 

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Literature cited

  1. 1.
    G. A. Nikiforov, B. D. Sviridov, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 558 (1968).Google Scholar
  2. 2.
    B. D. Sviridov, G. A. Nikiforov, and V. V. Ershov, ibid., 1862 (1969).Google Scholar
  3. 3.
    B. D. Sviridov, G. A. Nikiforov, and V. V. Ershov, ibid., 2388 (1970).Google Scholar
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    V. S. Aksenov, in: Contemporary Problems in Organic Chemistry [in Russian], K. A. Ogloblina (editor), LGU (1971), p. 16.Google Scholar
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    I. S. Belostotskaya, Dissertation [in Russian], Moscow (1968).Google Scholar
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    H. Frey, Trans. Faraday Soc.,58, 516 (1962).Google Scholar
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    M. Flawers and H. Frey, J. Chem. Soc., 3547 (1961).Google Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • G. A. Nikiforov
    • 1
  • B. D. Sviridov
    • 1
  • V. V. Ershov
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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