Conclusions
1-Alkoxymethyl-substituted 1-bromoallenes react with primary and secondary amines by the usual scheme of nucleophilic substitution and lead to the formation of polyfunctional acetylenic compounds, which excludes the carbene mechanism of similar reactions.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 369–373, February, 1974.
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Mavrov, M.V., Rodionov, A.P. & Kucherov, V.F. Nucleophilic replacement of bromine in 1-bromo-1-alkoxymethylallene compounds by amines. Russ Chem Bull 23, 335–338 (1974). https://doi.org/10.1007/BF00924682
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DOI: https://doi.org/10.1007/BF00924682