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Hydrogenolysis of gem-dimethylcyclobutane on group VIII noble metals

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the hydrogenolysis of gem-dimethylcyclobutane in the presence of Pt, Pd, Rh, Ir, and Ru, deposited on active charcoal.

  2. 2.

    On all of the studied catalysts the hydrogenolysis of gem-dimethylcyclobutane proceeds selectively at the unshielded bond, with the formation of 2,2-dimethylbutane.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    O. V. Bragin, E. G. Khelkovskaya-Sergeeva, S. V. Zotova, É. I. Vostokova & A. L. Liberman

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  1. O. V. Bragin
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  2. E. G. Khelkovskaya-Sergeeva
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  3. S. V. Zotova
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  4. É. I. Vostokova
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  5. A. L. Liberman
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 363–365, February, 1974.

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Bragin, O.V., Khelkovskaya-Sergeeva, E.G., Zotova, S.V. et al. Hydrogenolysis of gem-dimethylcyclobutane on group VIII noble metals. Russ Chem Bull 23, 329–331 (1974). https://doi.org/10.1007/BF00924680

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  • DOI: https://doi.org/10.1007/BF00924680

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