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Microcalorimetric investigation of the interaction of polystyrene, poly-N-vinylcarbazole, and their monomer analogs with antimony trichloride

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The equilibrium constants and thermodynamic parameters of complexes of SbCl3 with cumene, polystyrene, N-propylearbazole, and poly-N-vinylcarbazole were measured by the method of microcalorimetry. The thermodynamic parameters of the complexes are related by an isokinetic function; the isoequilibrium temperature is 179°K.

  2. 2.

    The higher equilibrium constants of the polymer complexes in comparison with the monomer complexes are due to steric factors.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry, Siberian Branch of the Academy of Sciences of the USSR, Tomsk

    A. S. Vavilkin, Yu. K. Maksyutin & I. G. Orlov

Authors
  1. A. S. Vavilkin
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  2. Yu. K. Maksyutin
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  3. I. G. Orlov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 360–362, February, 1974.

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Vavilkin, A.S., Maksyutin, Y.K. & Orlov, I.G. Microcalorimetric investigation of the interaction of polystyrene, poly-N-vinylcarbazole, and their monomer analogs with antimony trichloride. Russ Chem Bull 23, 326–328 (1974). https://doi.org/10.1007/BF00924679

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  • DOI: https://doi.org/10.1007/BF00924679

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