Skip to main content
SpringerLink
Log in

Mutarotation of β-D-arabinose in the presence of aliphatic-aromatic amino alcohols as catalysts

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The rate constants of the mutarotation ofβ-D-arabinose in 50% aqueous ethanol in the presence of the investigated catalysts obey the Bronsted function withβ = 0.84±0.01 at 20°.

  2. 2.

    The thermodynamic parameters of the activation of the mutarotation ofβ-D-arabinose under the action of the investigated catalysts are related by an isokinetic function (β = 250 ± 2K).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. H. Schmid, Monatsch. Chem.,94, 1206 (1963).

    Google Scholar 

  2. V. A. Pavlov, E. I. Klabunovskii, A. A. Balandin, E. M. Cherkasova, A. V. Sablin, Yu. I. Petrov, and I. P. Murina, Zh. Fiz. Khim.,42, 2481 (1968).

    Google Scholar 

  3. E. M. Cherkasova, Dissertation [in Russian], Moscow (1963).

  4. I. P. Murina, E. I. Klabunovskii, E. Ya. Borisova, and E. M. Cherkasova, Izv. Akad. Nauk SSSR, Ser. Khim., 1683 (1973).

  5. V. A. Pavlov, E. I. Klabunovskii, and A. A. Balandin, Kinetika i Kataliz,7, 551 (1966); Zh. Fiz. Khim.,42, 2475 (1968).

    Google Scholar 

  6. J. E. Leffler, J. Org. Chem.,20, 1202 (1955).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    I. P. Murina, E. I. Klabunovskii, V. A. Pavlov & E. M. Cherkasova

  2. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR

    I. P. Murina, E. I. Klabunovskii, V. A. Pavlov & E. M. Cherkasova

Authors
  1. I. P. Murina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. I. Klabunovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. A. Pavlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. M. Cherkasova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 333–337, February, 1974.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Murina, I.P., Klabunovskii, E.I., Pavlov, V.A. et al. Mutarotation of β-D-arabinose in the presence of aliphatic-aromatic amino alcohols as catalysts. Russ Chem Bull 23, 303–306 (1974). https://doi.org/10.1007/BF00924674

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00924674

Keywords

Search

Navigation