Conclusions
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1.
Dialkyl sulfites in liquids, vapors, and solutions are represented by structures with trans-trans- and trans-gauche-conformations of the chain R-O-S-O-R.
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2.
Diaryl sulfites exist in a trans-gauche conformation.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 318–323, February, 1974.
The authors would like to express their gratitude to B. A. Arbuzov for his constant attention to the work.
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Yuldasheva, L.K., Timosheva, A.P., Remizov, A.B. et al. Conformations of acyclic sulfites. Russ Chem Bull 23, 289–293 (1974). https://doi.org/10.1007/BF00924671
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DOI: https://doi.org/10.1007/BF00924671