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Bromide complexes of ruthenium (IV) in aqueous solutions

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The interaction of perchlorate solutions of Ru(IV) with Br− at room temperature and an ionic strength 4.0 M (NaClO4, NaBr) was studied spectrophotometrically in the interval of Br− concentrations 0.00–4.00 M.

  2. 2.

    Equilibrium in solutions with Br− contents 0.12–3.90 M is established within six months, while in solutions with Br− concentrations < 0.10 Mastate of equilibrium is not reached in 10 months.

  3. 3.

    The concentration conditions of predominant existence of the complex with composition [Ru2OBr8-(H2O)2]2− (or [RuOBr4]−) were established; its optical characteristics were determined, and the number of bromide ions participating in its formation was calculated.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    I. P. Alimarin, V. I. Shlenskaya, G. V. Pichugina & V. P. Khvostova

Authors
  1. I. P. Alimarin
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  2. V. I. Shlenskaya
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  3. G. V. Pichugina
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  4. V. P. Khvostova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Knimicheskaya, No. 2, pp. 305–309, February, 1974.

Deceased.

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Alimarin, I.P., Shlenskaya, V.I., Pichugina, G.V. et al. Bromide complexes of ruthenium (IV) in aqueous solutions. Russ Chem Bull 23, 277–281 (1974). https://doi.org/10.1007/BF00924668

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  • DOI: https://doi.org/10.1007/BF00924668

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