Skip to main content
SpringerLink
Log in

Temperature dependence of the rate of rapid reactions of proton transfer in aqueous solution

Communication 1. Proton transfer from aqua-ions of transition metals to the dianion of dibromocresolsulfophthalein

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The kinetics of the reactions of proton transfer from aqua-complexes of transition metals to the dianion of dibromocresolsulfophthalein in aqueous solution at temperatures from 8 to 50° was studied by the temperature jump method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. M. Eigen, Angew. Chem.,15, 489 (1963).

    Google Scholar 

  2. E. Koldin, Rapid Reactions in Solution [Russian translation], Mir (1966).

  3. L. A. Katsman, M. N. Vargaftik, and Ya. K. Syrkin, Dokl. Akad. Nauk SSSR,206, 645 (1972).

    Google Scholar 

  4. D. Wild, Methods of Searching for the Extreme [Russian translation], Nauka (1967).

  5. F. Ephraim, Ber.,56, 1536 (1923).

    Google Scholar 

  6. L. A. Katsman, M. N. Vargaftik, A. P. Belov, and Ya. K. Syrkin, Izv. Akad. Nauk SSSR, Ser. Khim., 1091 (1971).

  7. M. N. Vargaftik, V. A. Igoshin, and Ya. K. Syrkin, ibid., 1426 (1972).

  8. S. M. Smirnov and P. V. Terent'ev, Generators of High-Voltage Pulses [in Russian], Énergiya (1964).

  9. D. D. Perrin, J. Chem. Soc., 4500 (1962); 2197 (1962); 3644 (1964).

  10. J. A. Bolzan and A. J. Arvia, Electrochim. Acta,7, 589 (1962).

    Google Scholar 

  11. L. A. Katsman, M. N. Vargaftik, and Ya. K. Syrkin, Izv. Akad. Nauk SSSR, Ser. Khim., 1424 (1972).

  12. The Chemist's Handbook [in Russian], Vol. 3, Goskhimizdat (1952), p. 513.

  13. M. Eigen and W. Kruse, Z. Naturforsch.,b18, 857 (1963).

    Google Scholar 

  14. L. G. Sillenand, A. E. Martell, Stability Constants, Spec. Publ., No. 17, London (1964).

  15. S. C. Chan and K. J. Hui, Austral. J. Chem.,21, 3061 (1968).

    Google Scholar 

  16. A. J. Cunningham, D. A. House, and H. K. J. Powell, ibid.,23, 23 (1971).

    Google Scholar 

  17. M. Eigen and L. De Maeyer, Proc. Roy. Soc.,A 247, 505 (1958).

    Google Scholar 

  18. Yu. A. Makashev, Dissertation [in Russian], Leningrad (1972).

  19. R. Bell, Proton in Chemistry, New York (1959).

  20. R. Pearson, J. Am. Chem. Soc.,70, 204 (1948).

    Google Scholar 

  21. E. Lewis and L. Funderbruk, ibid.,89, 2322 (1967).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR

    L. A. Katsman, M. N. Vargaftik & Ya. K. Syrkin

Authors
  1. L. A. Katsman
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. N. Vargaftik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ya. K. Syrkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 299–305, February, 1974.

Deceased.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Katsman, L.A., Vargaftik, M.N. & Syrkin, Y.K. Temperature dependence of the rate of rapid reactions of proton transfer in aqueous solution. Russ Chem Bull 23, 271–276 (1974). https://doi.org/10.1007/BF00924667

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00924667

Keywords

Search

Navigation