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Synthesis and study of the thermal stability of lithium perxenonate

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    High-purity lithium perxenonate Li4XeO8· 2H2O was synthesized.

  2. 2.

    The thermal stability of lithium perxenonate was studied by the methods of weight loss of the sample under isothermal conditions, differential thermal and gravimetric analyses.

  3. 3.

    The temperatures of the decomposition of lithium perxenonate depend substantially on the conditions of production and preliminary drying of the preparation.

  4. 4.

    The kinetics of the thermal decomposition of lithium perxenonate were studied, and the activation energy, equal to 55.7 kcal/mole, was determined.

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Literature cited

  1. E. N. Appelman, J. G. Malm, and E. D. Joly, Preparative Inorganic Reactions, Vol. 2, New York-London (1965), p. 341.

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  2. I. S. Kirin, Yu. K. Gusev, V. K. Isupov, L. I. Molkanov, V. Ya. Mishin, and A. V. Krupmskaya, Zh. Neorg. Khim.,16, 2916 (1971).

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  3. L. N. Gal'perin, Zh. Fiz. Khim.,34, 2294 (1962).

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  4. Heterogeneous Chemical Reactions [in Russian], Nauka i Tekhnika, Minsk (1970).

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Author information

Authors and Affiliations

  1. Leningrad Institute of Nuclear Physics, Academy of Sciences of the USSR, Gatchina

    N. N. Aleinikov, V. K. Isupov, I. S. Kirin, B. L. Korsunskii & F. I. Dubovitskii

  2. Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    N. N. Aleinikov, V. K. Isupov, I. S. Kirin, B. L. Korsunskii & F. I. Dubovitskii

Authors
  1. N. N. Aleinikov
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  2. V. K. Isupov
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  3. I. S. Kirin
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  4. B. L. Korsunskii
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  5. F. I. Dubovitskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 278–281, February, 1974.

The authors would like to express their sincere gratitude to Yu. K. Gusev for his valuable advice and constant attention to the work.

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Aleinikov, N.N., Isupov, V.K., Kirin, I.S. et al. Synthesis and study of the thermal stability of lithium perxenonate. Russ Chem Bull 23, 250–253 (1974). https://doi.org/10.1007/BF00924662

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  • DOI: https://doi.org/10.1007/BF00924662

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