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The photochemical reduction of heteroacidodiamminedihydroxo-compounds of platinum (IV)

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Diamminedihydroxo-compounds of Pt(IV) with nonsymmetrical coordination NO2-Pt-X were synthesized, where X = Cl−, Br−, and SCN−.

  2. 2.

    The synthesized compounds undergo photochemical reduction to compounds of Pt(II). Possible mechanisms of the photoinduced reaction are discussed.

  3. 3.

    The compounds (NH3)2NO2X(OH)2Pt are arranged in the following series with respect to rate of photodecomposition: Br− > Cl− > SCN−.

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Literature cited

  1. I. I. Chernyaev, Izv. In-ta po Izucheniyu Platiny AN SSSR,5, 102;6, 55 (1927).

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  4. I. I. Chernyaev and S. I. Khorunzhenkova, Izv. In-ta po Izucheniyu Platiny AN SSSR,7, 98 (1929).

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  5. A. A. Grinberg, Introduction to the Chemistry of Complex Compounds [in Russian], Khimiya, Leningrad (1971), p. 29.

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  6. R. Robinson and R. Stokes, Solutions of Electrolytes [Russian translation], IL (1963), p. 537.

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Author information

Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    A. G. Samatov, N. N. Zheligovskaya & Vikt I. Spitsyn

Authors
  1. A. G. Samatov
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  2. N. N. Zheligovskaya
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  3. Vikt I. Spitsyn
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 274–277, February, 1974.

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Samatov, A.G., Zheligovskaya, N.N. & Spitsyn, V.I. The photochemical reduction of heteroacidodiamminedihydroxo-compounds of platinum (IV). Russ Chem Bull 23, 246–249 (1974). https://doi.org/10.1007/BF00924661

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  • DOI: https://doi.org/10.1007/BF00924661

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