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Spectrophotometric investigation of the equilibria in chloride solutions of ruthenium (IV)

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The interaction of an aqua-complex of Ru(IV) with the chloride ion was studied according to the electronic spectra at room temperature and an ionic strength of 4.0 M (HClO4, HCl).

  2. 2.

    The concentration conditions of existence of a complex with the presumed composition [Ru2OCl8(H2O)2]2− or [RuOCl4]2−) were determined, and its conditional constant of formation was calculated.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    V. I. Shlenskaya, G. V. Pichugina, V. P. Khvostova & I. P. Alimarin

Authors
  1. V. I. Shlenskaya
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  2. G. V. Pichugina
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  3. V. P. Khvostova
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  4. I. P. Alimarin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 268–271, February, 1974.

Deceased.

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Shlenskaya, V.I., Pichugina, G.V., Khvostova, V.P. et al. Spectrophotometric investigation of the equilibria in chloride solutions of ruthenium (IV). Russ Chem Bull 23, 240–242 (1974). https://doi.org/10.1007/BF00924659

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  • DOI: https://doi.org/10.1007/BF00924659

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