Skip to main content
SpringerLink
Log in

Mechanism for exchange of heterooeganic fragment between oxygen atoms of -O-N-O group in nitronic acid esters

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The DNMR method was used to study the 1,3-(O,O) migration of the heteroorganic fragment in the diethylboron and trimethylsilyl esters of bis(carbomethoxymethane)nitronic acid, and it was shown that the migration is accomplished via a multicenter cyclic transition state.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. M. Ya. Myagi, É. G. Lippmaa, S. L. Ioffe, V. A. Tartakovskii, A. S. Shashkov, B. N. Khasapov, and L. M. Makarenkova, Izv. Akad. Nauk SSSR, Ser. Khim.,1973, 1431.

  2. S. L. Ioffe, L. M. Leont'eva, A. L. Blyumenfel'd, O. P. Shitov, and V. A. Tartakovskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 1659.

  3. S. L. Ioffe, A. L. Blyumenfel'd, A. S. Shashkov, L. M. Makarenkova, and V. A. Tartakovskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 2320.

  4. A. L. Blyumenfel'd, A. S. Shashkov, S. L. Ioffe, O. B. Belkina, L. M. Makarenkova, and V. A. Tartakovskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 2543.

  5. H. J. Beich and D. A. Murcia, J. Am. Chem. Soc.,95, 3418 (1973).

    Google Scholar 

  6. S. L. Ioffe, V. M. Shitkin, B. N. Khasapov, M. V. Kashutina, V. A. Tartakovskii, M. Ya. Myagi, and É. G. Lippmaa, Izv. Akad. Nauk SSSR, Ser. Khim.,1973, 2146.

  7. V. M. Shitkin, S. L. loffe, M. V. Kashutina, and V. A. Tartakovskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 2266.

  8. V. I. Erashko, S. A. Shevelev, A. A. Fainzil'berg, M. Ya. Myagi, and É. G. Lippmaa, Izv. Akad. Nauk SSSR, Ser. Khim.,1970, 958.

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    S. L. Ioffe, A. S. Shashkov, A. L. Blyumenfel'd & K. M. Litvak

Authors
  1. S. L. Ioffe
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. S. Shashkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. L. Blyumenfel'd
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. M. Litvak
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2836–2838, December, 1977.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ioffe, S.L., Shashkov, A.S., Blyumenfel'd, A.L. et al. Mechanism for exchange of heterooeganic fragment between oxygen atoms of -O-N-O group in nitronic acid esters. Russ Chem Bull 26, 2625–2627 (1977). https://doi.org/10.1007/BF00924590

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00924590

Keywords

Search

Navigation