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Methylation of carbohydrates with methyl iodide in presence of dimsilpotassium

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A modification of the Hakomori method was proposed for the methylation of carbohydrates, which includes the generation of methylsulfinyl anion using potassium tert-butoxide.

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Literature cited

  1. S. Hakomori, J. Biochem. (Tokyo),55, 205 (1964).

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Authors and Affiliations

  1. M. M. Shemyakin Institute of Bioorganic Chemistry, Academy of Sciences of the USSR, Moscow

    N. V. Bovin, V. A. Nesmeyanov & A. Ya. Khorlin

Authors
  1. N. V. Bovin
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  2. V. A. Nesmeyanov
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  3. A. Ya. Khorlin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2834–2836, December, 1977.

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Bovin, N.V., Nesmeyanov, V.A. & Khorlin, A.Y. Methylation of carbohydrates with methyl iodide in presence of dimsilpotassium. Russ Chem Bull 26, 2622–2624 (1977). https://doi.org/10.1007/BF00924589

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  • DOI: https://doi.org/10.1007/BF00924589

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