Conclusions
The anodic trifluoromemylation of ethylene, vinylidene fluoride, and dimeoiyl maleate was effected, and the role played by the “head to head” doubling of the olefins in forming the dimeric products was shown.
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Literature cited
R. Lindsey and M. Peterson, J. Am. Chem. Soc.,81, 2073 (1959).
L. A. Mirkind and M. Ya. Fioshin, Zh. Fiz. Khim.,38, 2223 (1964).
K. G. Karapetyan, L. S. Kanevskii, A. M. Skundin, and Yu. B. Vasil'ev, Elektrokhimiya,12, 662 (1976).
C. T. Brooks and P. L. Coe, J. Chem. Soc. Chem. Commun.,1974, 323.
A. R. Hands, J. Chem. Soc.,1964, 1181.
G. L. Fleming, R. N. Haszeldine, and A. E. Tipping, J. Chem. Soc. Perkin Trans, 1,1973, 574.
J. M. Teddev, J. C. Walton, and K. D. R. Winton, J. Chem. Soc. Faraday Trans, 1,68, 1866 (1972).
W. B. Smith and H. G. Gilde, J. Am. Chem. Soc.,81, 5325 (1959).
W. R. Hashek and W. C. Smith, J. Am. Chem. Soc.,82, 544 (1960).
M. Hauptschein, M. Braid, and F. E. Fawlor, J. Am. Chem. Soc.,80, 846 (1958).
N. B. Kaz'mina, G. S. Krasnikova, E. P. Lur'e, E. I. Mysov, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 2525.
Dictionary of Organic Compounds [Russian translation], Vol. 2, IL (1949), p. 90.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2825–2827, December, 1977.
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Grinberg, V.A., Polishchuk, V.R., Mysov, E.I. et al. Electrochemical fluoroalkylation of ethylene. Russ Chem Bull 26, 2615–2617 (1977). https://doi.org/10.1007/BF00924586
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DOI: https://doi.org/10.1007/BF00924586