Synthesis and polymerization of unsaturated derivatives of adamantane

  • S. S. Novikov
  • A. P. Khardin
  • S. S. Radchenko
  • S. G. Zlotin
  • B. S. Orlinson
Organic Chemistry
  • 47 Downloads

Conclusions

  1. 1.

    The introduction of the adamantyl radical to the molecule of methacrylates and vinyl esters of carboxylic acids leads to an increase in their polymerizability.

     
  2. 2.

    With increase in the distance of adamantyl radical from the double bond of the monomer, the polymerizability of the latter decreases.

     

Keywords

Polymerization Ester Double Bond Vinyl Carboxylic Acid 

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Literature cited

  1. 1.
    US Pat. No. 3378587 (1967); Ref. Zh. Khim., 23N149P (1969). French Pat. No. 1565698, Chem. Abstr.,71, 125245f (1969); D. E. Montgomery, K. Tregonning, and P. R. Blaray, Polymer,13, 43 (1972); H. J. Storesund, Tetrahedron Lett., 3911 (1971); S. Moon and A. Schwarz, J. Polym. Sci., A-1,8, 3665 (1970).Google Scholar
  2. 2.
    US Pat. No. 3342880 (1963); Ref. Zh. Khim., 14S220P (1969).Google Scholar
  3. 3.
    S. S. Novikov, A. P. Khardin, S. S. Radchenko, and Yu. N. Kargin, Inventor's Cert. No. 490795, May 21 (1973); Byul. Izobr., No. 41, 96 (1975).Google Scholar
  4. 4.
    F. N. Stepanov and G. I. Danilenko, Zh. Org. Khim.,2, 1630 (1966).Google Scholar
  5. 5.
    D. Swern and E. Jordan, Organic Syntheses, Coll. Vol. 4, J. Wiley and Sons, N. Y.-Sydney (1963), p. 977.Google Scholar
  6. 6.
    C. Walling, Free Radicals in Solution, Wiley (1957).Google Scholar
  7. 7.
    H. Stetter, M. Schwarz, and A. Hirschborn, Chem. Ber.,92, 1629 (1959).Google Scholar
  8. 8.
    H. Stetter and I. Mayer, Chem. Ber.,95, 667 (1962).Google Scholar
  9. 9.
    H. Stetter and G. Wulf, Chem. Ber.,93, 1366 (1960).Google Scholar
  10. 10.
    K. Bott and N. Neiiman, Angew. Chem.,78, 932 (1966).Google Scholar

Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • S. S. Novikov
    • 1
  • A. P. Khardin
    • 1
  • S. S. Radchenko
    • 1
  • S. G. Zlotin
    • 1
  • B. S. Orlinson
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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