Conclusions
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1.
Rate constants have been measured for the recombinational desorption of theα andβ forms of nitrogen from the platinum surface.
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2.
A mechanism for the recombination of theα form of nitrogen has been proposed on the assumption that excited nitrogen molecules will form on the Pt surface.
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3.
The method of isotopic displacement of14N and15N atoms has been used to show that the platinum surface is nonuniform with respect to the adsorption of theα form of nitrogen.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2682–2687, December, 1978.
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Sklyarov, A.V., Dangyan, T.M., Kislyuk, M.U. et al. Recombinational desorption of nitrogen atoms from a platinum surface. Russ Chem Bull 26, 2478–2483 (1977). https://doi.org/10.1007/BF00924548
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DOI: https://doi.org/10.1007/BF00924548