Conclusions
The telomerization of propylene with methyl dichloroacetate includes chain transfer via the C-H and C-Cl bonds, and leads to the formation of four series of telomers, the methyl esters of chloro-substituted acids of type X[CH(CH3)CH2]nCClYCO2CH3 (X, Y=H, Cl), and also of the telomeric esters of the higher alcohols and dichloroacetic acid.
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Literature cited
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2150–2152, September, 1977.
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Moskalenko, M.A., Terent'ev, A.B. Telomerization of propylene with methyl dichloroacetate. Russ Chem Bull 26, 1992–1994 (1977). https://doi.org/10.1007/BF00924414
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DOI: https://doi.org/10.1007/BF00924414