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Replacement of carbon monoxide by π-ligands in fluorinated iron complex

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The π-allylidene complex is formed in the photochemical reaction of\(\begin{array}{*{20}c} {(CF_3 )_2 C = C---C(CF_3 ) = CF_2 } \\ | \\ {(\pi - C_5 H_5 )Fe(CO)_2 } \\ \end{array} \) with 1,3-butadiene and 1,3-cyclohexadiene, with subsequent replacement of the carbonyl group by the appropriate ligand.

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Literature cited

  1. A. N. Nesmeyanov, N. E. Kolobova, I. B. Zlotina, B. V. Lokshin, I. F. Leshcheva, G. K. Znobina, and K. N. Anisimov, Izv. Akad. Nauk SSSR, Ser. Khim., 1124 (1976).

  2. A. N. Nesmeyanov, N. E. Kolobova, I. B. Slotina, L. V. Ivanova, and K. N. Anisimov, Izv. Akad. Nauk SSSR, Ser. Khim., 707 (1977).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. E. Kolobova, I. B. Zlotina & I. I. Ivanova

Authors
  1. N. E. Kolobova
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  2. I. B. Zlotina
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  3. I. I. Ivanova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2130–2131, September, 1977.

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Kolobova, N.E., Zlotina, I.B. & Ivanova, I.I. Replacement of carbon monoxide by π-ligands in fluorinated iron complex. Russ Chem Bull 26, 1973–1974 (1977). https://doi.org/10.1007/BF00924407

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  • DOI: https://doi.org/10.1007/BF00924407

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