Conclusions
The radioactive isotope method was used to study the adsorption of various anions of phosphoric, phosphorous, and hypophosphorous acids on negatively and positively charged copper, and it was shown that the corresponding adsorption values change oppositely to the sums of the absolute values of the charges of all of the atoms of the anion, which were calculated by the CNDO/2 method.
Literature cited
Chemistry Handbook [in Russian], Vol. 3, Khimiya, Moscow-Leningrad (1964), p. 78.
M. A. Landau, A. V. Fokin, and A. S. Kabankin, Izv. Akad. Nauk SSSR, Ser. Khim., 2486 (1973).
M. A. Landau, V. V. Sheluchenko, and S. S. Dubov, Dokl. Akad. Nauk SSSR,182, 134 (1968); Zh. Strukt. Khim.,11, 513 (1970).
M. N. Bakirov and R. S. Vakhidov, Tr. Ufim. Aviats. Inst., No. 65, 77 (1973); Dokl. Akad. Nauk SSSR,216, 1312 (1974); Elektrokhimiya,11, 282 (1975).
J. A. Pople and G. A. Segal, J. Chem. Phys.,44, 3289 (1966); D. P. Santry and G. A. Segal, J. Chem. Phys.,47, 158 (1967).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2121–2124, September, 1977.
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Bakirov, M.N., Vakhidov, R.S., Ioslovich, N.V. et al. Adsorption of some phosphorus oxy anions on copper. Russ Chem Bull 26, 1965–1967 (1977). https://doi.org/10.1007/BF00924403
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DOI: https://doi.org/10.1007/BF00924403