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Barrier of rotation around C-N bond in 1-(N,N-dimethylcarbamoyl)-π-cyclopentadienyl-π-(3)-1, 2-dicarbollylcobalt

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The barriers of rotation around the C-N bond in the amides C5H5CoB9H9C2HCON(CH3)2, 1-(CH3)2NCO-1, 2-B10C2H11 and 1-(CH3)2NCO-1,7-B10C2H11 are substantially lower than in ordinary amides.

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Literature cited

  1. C. H. Bushweller, C. Y. Wang, W. J. Dewkett, W. Anderson, S. A. Daniels, and H. Beall, J. Am. Chem. Soc.,96, 1589 (1974).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. I. Zakharkin, R. Kh. Bikkineev & V. A. Antonovich

Authors
  1. L. I. Zakharkin
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  2. R. Kh. Bikkineev
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  3. V. A. Antonovich
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2119–2120, September, 1977.

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Zakharkin, L.I., Bikkineev, R.K. & Antonovich, V.A. Barrier of rotation around C-N bond in 1-(N,N-dimethylcarbamoyl)-π-cyclopentadienyl-π-(3)-1, 2-dicarbollylcobalt. Russ Chem Bull 26, 1963–1965 (1977). https://doi.org/10.1007/BF00924402

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  • DOI: https://doi.org/10.1007/BF00924402

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