Conclusions
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1.
The complexes of CoCl2 with the anisidines (o- and p-) are catalysts for the hydrogenation of 1,3-pentadiene (50°, 100 gauge atm), while the complexes with aniline or o- and p-toluidine are catalytically inert.
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2.
The hydrogenation of 1,3-pentadiene is highly selective, with the predominant formation of trans-2-pentene. The reaction probably proceeds via the intermediate step of the hydride.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2112–2114, September, 1977.
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Freidlin, L.K., Gvinter, L.I., Ablov, A.V. et al. Catalytic properties of cobalt(II) complexes with aromatic amines. Russ Chem Bull 26, 1956–1958 (1977). https://doi.org/10.1007/BF00924399
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DOI: https://doi.org/10.1007/BF00924399