Conclusions
-
1.
We have prepared tetrakin(bromoacetylacetonato)zirconium and tetrakis(bromoacetylacetonato)hafnium by the action of N-bromosuccinimide on the metal tetrakis(acetylacetonates); in the presence of benzoyl peroxide the reaction forms unsymmetrical tetrachelates of zirconium and hafnium containing three brominated and one unsubstituted acetylacetonate ligands.
-
2.
We report the IR and UV spectra of the synthetic compounds.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
É. M. Brainina, M. Kh. Minacheva, Z. S. Klemenkova, and B. V. Lokshin, Izv. Akad. Nauk SSSR, Ser. Khim., 339 (1976).
É. M. Brainina and M. Kh. Minacheva, Izv. Akad. Nauk SSSR, Ser. Khim., 1596 (1975).
R. W. Kluiber, J. Am. Chem. Soc.,82, 4839 (1960).
J. P. Collman, R. A. Moss, H. Maltz, and C. C. Heindel, J. Am. Chem. Soc.,83, 531 (1961).
A. N. Nesmeyanov, A. Z. Rubezhov, S. P. Gubin, and Z. B. Mitroshina, Izv. Akad. Nauk SSSR, Ser. Khim., 739 (1966).
P. R. Singh and R. Sahai, Aust. J. Chem.,20, 639 (1967).
P. R. Singh and R. Sahai, Aust. J. Chem.,22, 628 (1969).
J. P. Collman, Angew. Chem.,77, 154 (1965).
R. P. Druden and A. Winston, J. Phys. Chem.,62, 635 (1958).
R. C. Fay and T. J. Pinnavaia, Inorg. Chem.,7, 508 (1968).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds [Russian translation], Mir (1966).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2081–2085, September, 1977.
We sincerely thank B. V. Lokshin for discussion of the UV and IR spectra.
Rights and permissions
About this article
Cite this article
Brainina, É.M., Strunkina, L.I. Bromination of acetylacetonato complexes of zirconium and hafnium by N-bromosuccinimide. Russ Chem Bull 26, 1925–1929 (1977). https://doi.org/10.1007/BF00924391
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00924391