Conclusions
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1.
Radical exchange between bis(triethylgermyl)mercury and mercury acetylacetonate is accompanied by demercuration and forms 2-(triethylgermoxy)pent-2-en-4-one, the cis isomer of which shows 1,5-migration of the Et3Ge group between the two oxygen atoms of the acetylacetonate moiety.
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2.
Mercuribis(diethyl malonate), mercuribis(ethyl cyanoacetate), mercuribis(malononitrile), and mercuribis(acetonitrile) easily undergo exchange reactions with bis(triethylgermyl)mercury; these are accompanied by demercuration.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2070–2076, September, 1977.
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Belousova, L.I., Kruglaya, O.A., Neretin, V.V. et al. Exchange reactions of bis(triethylgermyl)mercury with mercury derivatives of acetylacetone, diethyl malonate, and related compounds. Russ Chem Bull 26, 1915–1920 (1977). https://doi.org/10.1007/BF00924389
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DOI: https://doi.org/10.1007/BF00924389