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The reaction of fluorine-containing β-alkoxyvinyl ketones and β-diketones with isocyanides

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Isocyanides react with fluorine-containing vinyl ketones to form initially 1,4-dycloaddition products. If a mobile hydrogen atom is present in the cycloadduct rearrangement takes place to a product with a migrated multiple bond in the ring or to a linear dienecarboxamide (the result of double isomerization involving ring opening).

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. A. Simonyan, É. A. Avetisyan, Z. V. Safronova & N. P. Gambaryan

Authors
  1. L. A. Simonyan
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  2. É. A. Avetisyan
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  3. Z. V. Safronova
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  4. N. P. Gambaryan
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Additional information

Translated from Izvestiya Akademiya Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2061–2065, September, 1977.

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Simonyan, L.A., Avetisyan, É.A., Safronova, Z.V. et al. The reaction of fluorine-containing β-alkoxyvinyl ketones and β-diketones with isocyanides. Russ Chem Bull 26, 1906–1910 (1977). https://doi.org/10.1007/BF00924387

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  • DOI: https://doi.org/10.1007/BF00924387

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