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Synthesis of aliphatic α-iodonitro compounds, N-iodo-N-nitroamines, and N-iodoimides of of carboxylic acids

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of the potassium salts of polynitroalkanes, their functional derivatives, nitroamines, and imides of carboxylic acids with ICI in a medium of inert solvents or in water results in the formation of the corresponding α-iodonitro derivatives, N-iodo-N-nitroamines, and N-iodoimides of the carboxylic acids.

  2. 2.

    The possibility of the replacement of a mobile hydrogen by iodine when nitroform is reacted with iodine monochloride has been demonstrated.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. L. Fridman & S. S. Novikov

Authors
  1. A. L. Fridman
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  2. S. S. Novikov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2058–2061, September, 1977.

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Fridman, A.L., Novikov, S.S. Synthesis of aliphatic α-iodonitro compounds, N-iodo-N-nitroamines, and N-iodoimides of of carboxylic acids. Russ Chem Bull 26, 1903–1906 (1977). https://doi.org/10.1007/BF00924386

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  • DOI: https://doi.org/10.1007/BF00924386

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