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A radical-trap study of free-radical formation in aliphatic nitro compound reactions 2. Free-radical formation in reactions of tetranitromethane with α-nitrocarbanions in aprotic solvating solvents

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Radical-trap methods have been used to show the formation of short-lived R1R2ĊNO2 and NO .2 radicals in the reactions of tetranitromethane with α-nitrocarbanions R1B2CNO2 in aprotic solvating solvents.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    L. B. Okhlobystina & V. A. Tyurikov

  2. M. V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR

    L. B. Okhlobystina & V. A. Tyurikov

Authors
  1. L. B. Okhlobystina
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  2. V. A. Tyurikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2035–2041, September, 1977.

For the preceding communication cf. [1].

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Okhlobystina, L.B., Tyurikov, V.A. A radical-trap study of free-radical formation in aliphatic nitro compound reactions 2. Free-radical formation in reactions of tetranitromethane with α-nitrocarbanions in aprotic solvating solvents. Russ Chem Bull 26, 1881–1886 (1977). https://doi.org/10.1007/BF00924381

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  • DOI: https://doi.org/10.1007/BF00924381

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