Conclusions
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1.
Dipole moments and polarizability ellipsoids have been determined for the phosphorus bonds in 2-phenoxy-1,3,2-dioxaphosphorinanes.
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2.
It has been shown that the phenoxy groups in these compounds have cis-axial orientation, the plane of the benzene ring standing at right angles to the P-O-CAr bond plane.
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B. A. Arbuzov, R. P. Arshinova, S. G. Vul'fson, and E. T. Mukmenev, Izv. Akad. Nauk SSSR, Ser. Khim., 2426 (1973).
B. A. Arbuzov, S. G. Vul'fson (Vulfson), and R. P. Arshinova, Phosphorus,4, 221 (1974).
O. Exner and V. Jehlicka, Coll. Czech. Chem. Commun.,30, 639 (1965).
A. B. Remizov and T. G. Mannafov, Zh. Prikl. Spektrosk.,25, 467 (1976).
H. Poulet and J.-P. Mathieu, Vibration Spectra and Symmetry of Crystals, Gordon and Breach.
R. P. Arshinova, S. G. Vul'fson, S. D. Ibragimova, E. T. Mukmenev, and B. A. Arbuzov, Izv. Akad. Nauk SSSR, Ser. Khim., 1241 (1976).
B. A. Arbuzov, R. P. Arshinova, Yu. M. Mareev, I. Kh. Shakirov, and V. S. Vinogradova, Izv. Akad. Nauk SSSR, Ser. Khim., 665 (1974).
R. J. W. Le Fevre, Advances in Physical Organic Chemistry (ed. by V. Gold), Vol. 3, London-New York (1965), p. 1.
S. G. Vul'fson, G. Ya. Cheryukanova, G. A. Chmutova, and A. N. Vereshchagin, Dokl. Akad. Nauk SSSR,212, 621 (1973).
B. A. Arbuzov, S. G. Vul'fson, G. G. Butenko, O. A. Samarina, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 94 (1976).
A. B. Remizov, Zh. Prikl. Spektrosk.,22, 251 (1975).
A. B. Remizov and O. A. Samarina, Zh. Prikl. Spektrosk.,22, 870 (1975).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2006–2011, September, 1977.
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Arbuzov, B.A., Arshinova, R.P., Sorokina, T.D. et al. The geometrical structures of phosphorus-containing heterocycles 18. 2-Phenoxy-1,3,2-dioxaphosphorinanes. Russ Chem Bull 26, 1856–1861 (1977). https://doi.org/10.1007/BF00924376
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DOI: https://doi.org/10.1007/BF00924376