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Geometrical structures of the azines of substituted acetophenones

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

By drawing on measured values of dipole moments and Kerr constants and a study of vibrational spectra, it has been shown that the molecules of the symmetrical azines of the acetophenones exist as EE′ forms of the s-trans conformer, the angle of rotation of the azomethylidyne fragments around the N-N bond being 130±5° with the phenyl rings displaced out of the C=N bond planes by 35±5°.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    S. A. Flegontov, Z. S. Titova, S. G. Vul'fson, V. I. Savin & Yu. P. Kitaev

Authors
  1. S. A. Flegontov
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  2. Z. S. Titova
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  3. S. G. Vul'fson
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  4. V. I. Savin
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  5. Yu. P. Kitaev
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1996–1999, September, 1977.

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Flegontov, S.A., Titova, Z.S., Vul'fson, S.G. et al. Geometrical structures of the azines of substituted acetophenones. Russ Chem Bull 26, 1848–1851 (1977). https://doi.org/10.1007/BF00924374

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  • DOI: https://doi.org/10.1007/BF00924374

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