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Oxidation of bisbenzenechromium(0) by stable phenoxyl radical

  • A. Yu. Sorokin
  • Yu. A. Shevelev
  • G. A. Domrachev
Brief Communications
  • 18 Downloads

Conclusions

  1. 1.

    (C6H6)2Cr(0) is oxidized by the stable 2,4,6-tri-tert-butylphenoxyl radical to the saltlike bisbenzenechromium 2,4,6-tri-tert-butylphenolate.

     
  2. 2.

    It was shown that the phenolate can undergo dissociative sublimation.

     
  3. 3.

    The phenolate undergoes thermal decomposition by the disproportionation mechanism, in which the initial step is dissociation of the phenolate to (C6H6)2Cr(O) and the phenoxyl radical.

     

Keywords

Oxidation Phenolate C6H6 Thermal Decomposition Initial Step 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

  1. 1.
    E. O. Fischer and H. P. Fritz, Angew. Chem.,73, 353 (1961).Google Scholar
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    G. A. Rasuvaev and G. A. Domrachev, Tetrahedron,19, 341 (1963).Google Scholar
  3. 3.
    H. Yamazaki, M. Yamaguchi, and N. Hagahara, Mem. Inst. Sci. Ind. Res. Osaka Univ.,20, 107 (1963).Google Scholar
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    V. M. Fomin, Yu. A. Alexandrov, and V. A. Umilin, J. Organometal. Chem.,61, 262 (1973).Google Scholar
  5. 5.
    V. D. Pokhodenko, Phenoxyl Radicals [in Russian], Naukova Dumka, Kiev (1969).Google Scholar
  6. 6.
    E. O. Fischer and H. P. Kogler, Angew. Chem.,68, 462 (1956).Google Scholar
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    G. G. Petukhov, B. I. Rabosin, and A. N. Artemov, Zh. Obshch. Khim.,42, 2694 (1972).Google Scholar

Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • A. Yu. Sorokin
    • 1
  • Yu. A. Shevelev
    • 1
  • G. A. Domrachev
    • 1
  1. 1.Institute of ChemistryAcademy of Sciences of the USSRGorki

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