Conclusions
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1.
We obtained and characterized the stable mercury salt of difluoronitroacetic acid, which exists as the intramolecular donor-acceptor complex.
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2.
The alkylation of the mercury salt of difluoronitroacetic acid with alkylhalides in ether and acetonitrile was studied.
Literature cited
I.-L. Knunyants and A. V. Fokin, Dokl. Akad. Nauk SSSR,112, 67 (1957).
E. R. Bissel, Fluorine Chem. Rev.,4, 119 (1969).
E. R. Bissel, J. Org. Chem.,26, 5100 (1961).
A. V. Fokin, Yu. M. Kosyrev, I. N. Sorochkin, and V. P. Radchenko, Zh. Obshch. Khim.,37, 633 (1967).
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 707–710, March, 1978.
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Fokin, A.V., Komarov, V.A., Kolomiets, A.F. et al. Mercury salt of difluoronitroacetic acid. Russ Chem Bull 27, 612–615 (1978). https://doi.org/10.1007/BF00923957
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DOI: https://doi.org/10.1007/BF00923957