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Synthesis and decomposition of biscyclopentadienyl (methyl)vanadium chloride

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of Cp2VMe2 (Cp =cyclopentadienyl) with an equimolar amount of HCl gave Cp2V(Me)Cl.

  2. 2.

    Cp2V(Me)Cl decomposes with a retention of the biscyclopentadienyl structure and the insertion of a methyl group in the cyclopentadienyl ring.

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Literature cited

  1. G. A. Razuvaev, V. N. Latyaeva, L. I. Vyshinskaya, V. K. Cherkasov, S. P. Korneva, and N. N. Spiridonova, J. Organometal. Chem.,129, 169 (1977).

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  2. G. A. Razuvaev, V. P. Mar'in, S. P. Korneva, L. I. Vyshinskaya, V. K. Cherkasov, and O. N. Druzhkov, Dokl. Akad. Nauk SSSR,231, 626 (1976).

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Authors and Affiliations

  1. Institute of Chemistry, N. I. Lobachevskii Gorki State University, USSR

    G. A. Razuvaev, S. P. Korneva, L. I. Vyshinskaya, V. P. Mar'in & V. K. Cherkasov

Authors
  1. G. A. Razuvaev
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  2. S. P. Korneva
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  3. L. I. Vyshinskaya
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  4. V. P. Mar'in
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  5. V. K. Cherkasov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 700–702, March, 1978.

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Razuvaev, G.A., Korneva, S.P., Vyshinskaya, L.I. et al. Synthesis and decomposition of biscyclopentadienyl (methyl)vanadium chloride. Russ Chem Bull 27, 605–606 (1978). https://doi.org/10.1007/BF00923954

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  • DOI: https://doi.org/10.1007/BF00923954

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