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Use of statistical methods to prove the existence of aquo complexes in acid solutions of platinum(IV) hydroxo complexes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    On the basis of comparing the curves expressing the function: degree of formation of complexes vs acidity of solution, with the results of the statistical processing of the titration curves it must be considered as established that the mono- and diaquo complexes of platinum, APtX4H2OOH and PtX4(H2O2)2, where A = NH4, K, and X = Cl, Br, I, NO2, NO3, are formed in acid medium.

  2. 2.

    A variation of the standard statistical method was developed which permits using it for the results of the potentiometric determination of the acid dissociation constants of strong acids.

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Literature cited

  1. N. A. Chernova, Dissertation, Moscow (1970).

  2. N. S. Budanova and N. N. Zheligovskaya, VINITI, Dep. No. 5085-72; Ref. Zh., Khim., No. 9V138DP (1973).

  3. N. S. Budanova, N. N. Zheligovskaya, and V. I. Spitsyn, Izv. Akad. NaukSSSR, Ser. Khim., 1927 (1974).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    N. S. Budanova, N. N. Zheligovskaya, N. A. Chernova & V. I. Spitsyn

Authors
  1. N. S. Budanova
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  2. N. N. Zheligovskaya
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  3. N. A. Chernova
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  4. V. I. Spitsyn
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 670–673, March, 1978.

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Budanova, N.S., Zheligovskaya, N.N., Chernova, N.A. et al. Use of statistical methods to prove the existence of aquo complexes in acid solutions of platinum(IV) hydroxo complexes. Russ Chem Bull 27, 578–580 (1978). https://doi.org/10.1007/BF00923943

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  • DOI: https://doi.org/10.1007/BF00923943

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