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Synthesis and geometrical structure of 4-methyl-3-carene and certain of its derivatives

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    4-Methyl-3-carene, its epoxide, and adduct with dichlorocarbene have been synthesized.

  2. 2.

    4-Methyl-3-carene exists in a much flattened syn-boat conformation.

  3. 3.

    The cycloaddition products have trans configuration and anti-boat conformation with respect to the dimethylcyclopropane ring.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    L. K. Novikova, O. B. Skripnik, G. Sh. Bikbulatova, S. G. Vul'fson, Z. G. Isaeva & A. N. Vereshchagin

Authors
  1. L. K. Novikova
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  2. O. B. Skripnik
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  3. G. Sh. Bikbulatova
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  4. S. G. Vul'fson
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  5. Z. G. Isaeva
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  6. A. N. Vereshchagin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 605–609, March, 1978.

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Novikova, L.K., Skripnik, O.B., Bikbulatova, G.S. et al. Synthesis and geometrical structure of 4-methyl-3-carene and certain of its derivatives. Russ Chem Bull 27, 520–524 (1978). https://doi.org/10.1007/BF00923929

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  • DOI: https://doi.org/10.1007/BF00923929

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