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Equivalent equations for micropore adsorption

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Over a wide range of filling, and at definitely defined temperatures, micropore adsorptional equilibrium can be described with high accuracy by equations of different mathematical structure.

  2. 2.

    In the theory of micropore volume filling (TMVF), the thermal adsorption equation corresponds to a temperature invariant characteristic equation. This equivalent equation is part of TMVF and gives an alternate mathematical description of one aspect of the latter.

  3. 3.

    The thermal micropore adsorption equation proposed by Cohen, and independently by Kisarov, is the equivalent TMVF equation.

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Literature cited

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Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow

    M. M. Dubinin

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  1. M. M. Dubinin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 529–535, March, 1978.

The author would like to thank T. S. Yakubov for a discussion of the results obtained in the course of this work.

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Dubinin, M.M. Equivalent equations for micropore adsorption. Russ Chem Bull 27, 456–461 (1978). https://doi.org/10.1007/BF00923914

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  • DOI: https://doi.org/10.1007/BF00923914

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