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Ammonium perchloratoaluminates

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The authors have investigated the reaction of aluminum chloride with solutions of ammonium perchlorate in perchloric acid in absence of oxonium perchlorate. At a molar ratio NH4:Al=1 they obtained anhydrous tetraperchloratoaluminate solvated with perchloric acid; at a ratio NH4:Al=2, (NH4)2-Al(ClO4)5 crystallizes from perchloric acid; and at NH4∶Al=3, (NH4)3(ClO4)6 crystallizes.

  2. 2.

    By desolvation of the tetraperchloratoaluminate solvated with perchloric acid, they have obtained NH4Al(ClO4)4 in vacuum at 50–70°C.

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Literature cited

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Authors and Affiliations

  1. Institute of New Chemical Problems, Academy of Sciences of the USSR, Chernogolovka

    Z. K. Nikitina & V. Ya. Rosolovskii

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  1. Z. K. Nikitina
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  2. V. Ya. Rosolovskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 521–524, March, 1978.

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Nikitina, Z.K., Rosolovskii, V.Y. Ammonium perchloratoaluminates. Russ Chem Bull 27, 449–452 (1978). https://doi.org/10.1007/BF00923912

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  • DOI: https://doi.org/10.1007/BF00923912

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