Reaction of poly- and perfluoroalkyl perfluoroisopropyl ketones with secondary amines

  • Yu. Ya. Sud'enkov
  • T. P. Poltanova
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Conclusions

  1. 1.

    Poly- and perfluoroalkyl perfluoroisopropyl ketones react with morpholine to give the corresponding tertiary amines and 2-hydroperfluoropropane.

     
  2. 2.

    The reaction with diethylamine gradually changes from the “haloform” decomposition reaction to the reduction reaction with increase in the length of the fluoroalkyl substituent in the ketones.

     

Keywords

Ketone Reduction Reaction Decomposition Reaction Secondary Amine Morpholine 

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Literature cited

  1. 1.
    G. F. Ovchinnikov, Yu. Ya. Sud'enkov, and I. P. Kolenko, Zh. Vses. Khim. Obshchestva im. D. I. Mendeleeva,19, 105 (1974).Google Scholar
  2. 2.
    N. P. Gambaryan and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim.,1965, 722.Google Scholar
  3. 3.
    M. M. Joullie, J. Am. Chem. Soc.,77, 6662 (1955).Google Scholar
  4. 4.
    A. Ya. Yakubovich, A. P. Sergeev, andE. N. Fogel'zang, Zh. Obshch. Khim.,36, 1317 (1966).Google Scholar
  5. 5.
    I. P. Kolenko, V. S. Plashkin, and G. F. Ovchinnikov, Zh. Vses. Khim. Obshchestva im. D. I. Mendeleeva,19, 707 (1974).Google Scholar
  6. 6.
    R. D. Smith, F. S. Fawcett, and D. D. Coffman, J. Am. Chem. Soc.,84, 4235 (1962).Google Scholar

Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • Yu. Ya. Sud'enkov
    • 1
  • T. P. Poltanova
    • 1
  1. 1.Institute of ChemistryUral Scientific Center of the Academy of Sciences of the USSRSverdlovsk

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