Polarity, polarizability anisotropy, and structure of some compounds with a N-O bond

  • A. N. Vereshchagin
  • Yu. P. Artsybasheva
  • A. M. Kamalyutdinova
  • B. V. Ioffe
Brief Communications


  1. 1.

    It was established that the N-O bond in the O-methylhydroxylamine molecule has a low polarity (0.40 D) and a negative polarizability anisotropy (−0.32 Å3).

  2. 2.

    In O-methylacetone oxime and O-methoxyaziridines the C -O bond of the methoxy group and the unshared electron pair of nitrogen have the same syn orientation.



Nitrogen Anisotropy Methoxy Oxime Electron Pair 
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Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • A. N. Vereshchagin
    • 1
    • 2
  • Yu. P. Artsybasheva
    • 1
    • 2
  • A. M. Kamalyutdinova
    • 1
    • 2
  • B. V. Ioffe
    • 1
    • 2
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan Branch of the Academy of Sciences of the USSRUSSR
  2. 2.A. A. Zhdanov Leningrad State UniversityUSSR

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