Conclusions
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1.
The C-Hal bond of theα-haloethylbenzenes is rotated out of the ring plane by an angle of -50–70°.
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2.
α-Chloroisopropylbenzene and its bromo derivative exist as comformers with C-Cl bond shielding.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 354–359, February, 1978.
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Arbuzov, B.A., Khamatullina, I.M., Vul'fson, S.G. et al. Polarities, polarizability anisotropies, and geometrical structures of certain α-haloalkylbenzenes. Russ Chem Bull 27, 305–309 (1978). https://doi.org/10.1007/BF00923865
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DOI: https://doi.org/10.1007/BF00923865