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Decomposition of nitrogen-hydrogen complexes of decaborane(12). 2. An IR study of the mechanism of decomposition of decaborane(12) diammoniate

  • A. S. Rozenberg
Physical Chemistry
  • 59 Downloads

Conclusions

  1. 1.

    IR spectra for decaborane(12) diammoniate, and the products obtained at various stages in its decomposition, have been analyzed and interpreted.

     
  2. 2.

    The decomposition of decaborane(12) diammoniate probably proceeds through formation of a covalent B-N bond from a donor-acceptor B ← N bond.

     

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Literature cited

  1. 1.
    A. S. Rozenberg, G. N. Nechiporenko, and A. P. Alekseev, Izv. Akad. Nauk SSSR, Ser. Khim., 330 (1978).Google Scholar
  2. 2.
    R. J. Pace, J. Williams, and R. L. Williams, J. Chem. Soc., 2196 (1961).Google Scholar
  3. 3.
    J. Williams, R. L. Williams, and J. C. Whight, J. Chem. Soc., 5816 (1963).Google Scholar
  4. 4.
    R. L. Huckes, J. S. Smith, and E. W. Lowless, Production of the Boron and Related Research, New Hork, London (1967).Google Scholar
  5. 5.
    R. M. Adams, Boron, Metallo-Boron Compounds and Boranes, New York (1964).Google Scholar
  6. 6.
    B. M. Mikhailov, Chemistry of the Boranes [in Russian], Nauka (1967).Google Scholar
  7. 7.
    E. L. Muetterties, R. E. Merrfield, H. C. Miller, W. N. Knoth, and J. R. Dowing, J. Am. Chem. Soc.,84, 2506 (1962).Google Scholar
  8. 8.
    K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, Wiley (1963).Google Scholar
  9. 9.
    T. H. Rooling and D. F. Horing, J. Chem. Phys.,19, 594 (1951);22, 1926 (1957).Google Scholar
  10. 10.
    V. V. Zakharov, A. F. Zhigach, and B. S. Nikitin, Zh. Fiz. Khim.,48, 238 (1974).Google Scholar
  11. 11.
    W. R. Hertner and M. S. Raash, J. Am. Chem. Soc.,86, 3661 (1964).Google Scholar
  12. 12.
    R. S. Taylor and S. L. Cluff, Nature,182, 380 (1958).Google Scholar
  13. 13.
    K. Niedenzu and J. W. Dawson, Boron-Nitrogen Compounds, Springer-Verlag (1965).Google Scholar

Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • A. S. Rozenberg
    • 1
  1. 1.Branch of the Institute of Chemical PhysicsAcademy of Sciences of the USSRChernogolovka

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